Bài 15: Ý nghĩa là cách tính biến thiên Enthalpy phản ứng hóa học
Hướng dẫn giải Bài 2 (Trang 87 SGK Hóa 10, Bộ Cánh diều)
<p><strong>B&agrave;i 2 (Trang 87 SGK H&oacute;a 10, Bộ C&aacute;nh diều):</strong></p> <p>T&iacute;nh&nbsp;<math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi mathvariant="normal">r</mi></msub><mo>,</mo><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup></math>&nbsp;cho phản ứng sau dựa theo năng lượng li&ecirc;n kết.</p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>CH</mi><mn>4</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#8201;</mo><msub><mi mathvariant="normal">X</mi><mn>2</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>&#8594;</mo><mo>&#160;</mo><msub><mi>CH</mi><mn>3</mn></msub><mi mathvariant="normal">X</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mi>HX</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo></math></p> <p align="left">Với X = F, Cl, Br, I. Li&ecirc;n hệ giữa mức độ phản ứng (dựa theo <math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi mathvariant="normal">r</mi></msub><mo>,</mo><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup></math>) với t&iacute;nh phi kim (F &gt; Cl &gt; Br &gt; I). Tra c&aacute;c gi&aacute; trị năng lượng li&ecirc;n kết của Phụ lục 2, trang 118.</p> <p>&nbsp;</p> <p><span style="text-decoration: underline;"><em><strong>Hướng dẫn giải:</strong></em></span></p> <p><strong>- X&eacute;t X l&agrave; F</strong>, ta c&oacute;:</p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>CH</mi><mn>4</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">F</mi><mn>2</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>&#8594;</mo><mo>&#160;</mo><msub><mi>CH</mi><mn>3</mn></msub><mi mathvariant="normal">F</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mi>HF</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>4</mn></msub><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi mathvariant="normal">F</mi><mn>2</mn></msub><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><mi>HF</mi><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>3</mn></msub><mi mathvariant="normal">F</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">F</mi><mo>-</mo><mi mathvariant="normal">F</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">H</mi><mo>-</mo><mi mathvariant="normal">F</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">F</mi></mrow></msub><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#8201;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>159</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>565</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>485</mn><mo>)</mo><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mo>-</mo><mn>477</mn><mo>&#160;</mo><mi>kJ</mi><mo>.</mo></math></p> <p><strong>- X&eacute;t X l&agrave; Cl, </strong>ta c&oacute;<strong>:</strong></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>CH</mi><mn>4</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi>Cl</mi><mn>2</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>&#8594;</mo><mo>&#160;</mo><msub><mi>CH</mi><mn>3</mn></msub><mi>Cl</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mi>HCl</mi><mo>&#160;</mo><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi mathvariant="normal">f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>4</mn></msub><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>Cl</mi><mn>2</mn></msub><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><mi>HCl</mi><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>3</mn></msub><mi>Cl</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi>Cl</mi><mo>-</mo><mi>Cl</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">H</mi><mo>-</mo><mi>Cl</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi>Cl</mi></mrow></msub><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#8201;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>243</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>431</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>339</mn><mo>)</mo><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mo>-</mo><mn>113</mn><mo>&#160;</mo><mi>kJ</mi><mo>.</mo></math></p> <p>- <strong>X&eacute;t X l&agrave; Br</strong>, ta c&oacute;:</p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>CH</mi><mn>4</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi>Br</mi><mn>2</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>&#8594;</mo><mo>&#160;</mo><msub><mi>CH</mi><mn>3</mn></msub><mi>Br</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mi>HBr</mi><mo>&#160;</mo><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>4</mn></msub><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>Br</mi><mn>2</mn></msub><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><mi>HBr</mi><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>3</mn></msub><mi>Br</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi>Br</mi><mo>-</mo><mi>Br</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">H</mi><mo>-</mo><mi>Br</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi>Br</mi></mrow></msub><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#8201;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>193</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>364</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>276</mn><mo>)</mo><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mo>-</mo><mn>33</mn><mo>&#160;</mo><mi>kJ</mi><mo>.</mo></math></p> <p>- <strong>X&eacute;t X l&agrave; I</strong>, ta c&oacute;:</p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>CH</mi><mn>4</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">I</mi><mn>2</mn></msub><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>&#8594;</mo><mo>&#160;</mo><msub><mi>CH</mi><mn>3</mn></msub><mi mathvariant="normal">I</mi><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mi>HI</mi><mo>&#160;</mo><mo>(</mo><mi mathvariant="normal">g</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>4</mn></msub><mo>)</mo><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi mathvariant="normal">I</mi><mn>2</mn></msub><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><mi>HI</mi><mo>)</mo><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mi mathvariant="normal">b</mi></msub><mo>(</mo><msub><mi>CH</mi><mn>3</mn></msub><mi mathvariant="normal">I</mi><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">I</mi><mo>-</mo><mi mathvariant="normal">I</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><msub><mi>xE</mi><mrow><mi mathvariant="normal">H</mi><mo>-</mo><mi mathvariant="normal">I</mi></mrow></msub><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">H</mi></mrow></msub><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><msub><mi mathvariant="normal">E</mi><mrow><mi mathvariant="normal">C</mi><mo>-</mo><mi mathvariant="normal">I</mi></mrow></msub><mo>)</mo></math></p> <p><math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mo>&#8710;</mo><mi>f</mi></msub><msubsup><mi mathvariant="normal">H</mi><mn>298</mn><mn>0</mn></msubsup><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>4</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#8201;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>151</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>297</mn><mo>&#160;</mo><mo>-</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mo>(</mo><mn>3</mn><mi mathvariant="normal">x</mi><mn>414</mn><mo>&#160;</mo><mo>+</mo><mo>&#160;</mo><mn>1</mn><mi mathvariant="normal">x</mi><mn>240</mn><mo>)</mo><mo>&#160;</mo><mo>=</mo><mo>&#160;</mo><mn>28</mn><mo>&#160;</mo><mi>kJ</mi><mo>.</mo></math></p> <p>&rarr;Từ F đến I, t&iacute;nh phi kim giảm dần n&ecirc;n khả năng tham gia phản ứng giảm dần.</p>
Hướng dẫn giải Bài tập 2 (trang 87, Hóa lớp 10, Bộ Cánh diều)
GV: GV colearn
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Hướng dẫn giải Bài tập 2 (trang 87, Hóa lớp 10, Bộ Cánh diều)
GV: GV colearn